69. X. Zhang and L. L. Liu,*
A Free Aluminylene with Diverse σ-Donating and Doubly σ/π-Accepting Ligand Features for Transition Metals,
Angew. Chem. Int. Ed. 2021, 60, 27062-27069. DOI: 10.1002/anie.202111975 (Hot Paper)
68. S. Li; C. Hu; X. Cui; J. Zhang; L. L. Liu* and L. Wu,*
Site-Fixed Hydroboration of Terminal and Internal Alkenes Using BX3/iPr2NEt,
Angew. Chem. Int. Ed. 2021, 60, 26238-26245. DOI: 10.1002/anie.202111978
67. C. Tang; Y. Zhao; J. Wu; Z. Chen; L. L. Liu; Y.-Z. Tan, J. Zhu* and H. Xia,*
Releasing Antiaromaticity in Metal-Bridgehead Naphthalene,
J. Am. Chem. Soc. 2021, 143, 15587–15592. DOI: 10.1021/jacs.1c08106
(Highlighted by ChemistryViews)
66. R. Guo; T. Li; R. Wei; X. Zhang; Q. Li; L. L. Liu;* C. Tung and L. Kong,*
Boraiminolithium: An Iminoborane-Transfer Reagent,
J. Am. Chem. Soc. 2021, 143, 13483–13488. DOI: 10.1021/jacs.1c06152
(Highlighted by ChemistryViews)
65. X. Chen;+ C. Hu;+ X. Zhang; S. Liu; Y. Mei; G. Hu; L. L. Liu; Z. Li* and C. Su*
Reversible Stereoisomerization of 1,3-Diphosphetanes Revealed by a Single-Electron Redox Approach,
Inorg. Chem. 2021, 60, 5771–5778. DOI: 10.1021/acs.inorgchem.1c00064
(+ = equal contribution)
64. X. Yang; R. Wei; Y. Shi; L. L. Liu; Y. Wu,* Y. Zhao and D. W. Stephan,*
Oxyphosphoranes as Precursors to Bridging Phosphate-Catecholate Ligands,
Chem. Commun. 2021, 57, 1194-1197. DOI: 10.1039/D0CC07736D
(Selected as outside back cover)
63. L. Zhao;+ C. Hu;+ X. Cong; G. Deng; L. L. Liu; M. Luo and X. Zeng,*
Cyclic (Alkyl)(amino)carbene Ligand-Promoted Nitro Deoxygenative Hydroboration with Chromium Catalysis: Scope, Mechanism, and Applications,
J. Am. Chem. Soc. 2021, 143, 1618-1629. DOI: 10.1021/jacs.0c12318
(+ = equal contribution)
