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YEAR

2022

82. J. Li; Z. Lu and L. L. Liu,* 

A Free Phosphaborene Stable at Room Temperature,

J. Am. Chem. Soc. 2022, 144, 23691–23697. DOI: 10.1021/jacs.2c11878

(Highlighted by ChemistryViews)

(Peer-review report)

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81. X. Zhang;+ Y. Mei+ and L. L. Liu,* 

Free Aluminylenes: An Emerging Class of Compounds,

Chem. Eur. J. 2022, 28, e202202102. DOI: 10.1002/chem.202202102

(+ = equal contribution)

(Invited contribution)

(Peer-review report)

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80. M. Wu;+ Y. He;+ L. Zhang;+ R. Wei; D. Wang, J. Liu;* L. L. Liu and G. Tan,*

An Acyclic Silylone Stabilized by Mesoionic Carbene,

Eur. J. Inorg. Chem. 2022, 2022, e202200413. DOI: 10.1002/ejic.202200413

(+ = equal contribution)

(Invited contribution for Collection of EurJIC Talents)

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79. J. Li; Y. Mei and L. L. Liu,* 

An Isolable Phosphaborene Stabilized by an Intramolecular Lewis Base,

Eur. J. Inorg. Chem. 2022, 2022, e202200368. DOI: 10.1002/ejic.202200368

(Invited contribution for Collections of EurJIC Talents and Board Member Highlights)

(Peer-review report)

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78. S. Qiu; X. Zhang; C. Hu; H. Chu; Q. Li; D. A. Ruiz; L. L. Liu;* C.-H Tung and L. Kong,*

Unveiling Hetero-Enyne Reactivity of Aryliminoboranes: Dearomative Hetero-Diels-Alder-Like Reactions,

Angew. Chem. Int. Ed. 2022, 61, e202205814. DOI: 10.1002/anie.202205814 (Hot Paper)

(Peer-review report)

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77. R. Wei; S. Ju and L. L. Liu,

Free Metallophosphines: Extremely Electron-Rich Phosphorus Superbases that are Electronically and Sterically Tunable,

Angew. Chem. Int. Ed. 2022, 61, e202205618. DOI: 10.1002/anie.202205618 (Hot Paper)

(Highlighted by ChemViews)

(Peer-review report)

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76. S. Chen; L. Peng; Y. Liu; X. Gao; Y. Zhang; C. Tang; Z. Zhai; L. Yang; W. Wu; X. He; L. L. Liu; F. He and H. Xia,* 

Conjugated Polymers Based on Metalla-Aromatic Building Blocks,

Proc. Natl. Acad. Sci. U S A., 2022, 119, e2203701119. DOI: 10.1073/pnas.220370111

(Highlighted by ChemistryViews)

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75. Y. Wang; X. Zhang; T. Li; Q. Li; R. Wei; D. A. Ruiz; L. L. Liu;* C.-H. Tung and L. Kong,*

Crystalline Neutral Diboron Analogues of Cyclopropanes,

Angew. Chem. Int. Ed. 2022, 61e202117053. DOI: 10.1002/anie.202117053 (Hot Paper)

(Highlighted by ChemViews)

(Peer-review report)

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74. X. Zhang and L. L. Liu,*

Modulating the Frontier Orbitals of an Aluminylene for Facile Dearomatization of Inert Arenes,

Angew. Chem. Int. Ed. 2022, 61, e202116658. DOI: 10.1002/anie.202116658 (VIP)

(Peer-review report)

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73. C. Hu;+ X.-F. Wang;+ R. Wei; C. Hu; D. A. Ruiz; X.-Y. Chang and L. L. Liu,*

Crystalline Monometal-Substituted Free Carbenes,

Chem 2022, 8, 2278-2289. DOI: 10.1016/j.chempr.2022.06.003

(+ = equal contribution)

(Previewed by Sven Schneider in Chem entitled “Carbynes reloaded: Isolation of singlet metallocarbenes”)

(Peer-review report)

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72. Y. Mei; Z. Yan and L. L. Liu,*

Facile Synthesis of the Dicyanophosphide Anion via Electrochemical Activation of White Phosphorus: An Avenue to Organophosphorus Compounds,

J. Am. Chem. Soc. 2022, 144, 1517–1522. DOI: 10.1021/jacs.1c11087

(Peer-review report)

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71. B. Xu;+ W. Mao;+ C. Wu; J. Li; Z. Lu; M. Luo; L. L. Liu; L. Mao; D. Chen* and H. Xia,*

A One-Pot Strategy for the Synthesis of β-Substituted Rhoda- and Irida-Carbolong Complexes,

Chin. J. Chem. 2022, 40, 1777–1784. DOI: 10.1002/cjoc.202200179

(+ = equal contribution)

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70. R. Guo; X. Zhang; T. Li; Q. Li; D. A. Ruiz; L. L. Liu; C. Tung and L. Kong,*

Unraveling the Reactivity of a Cationic Iminoborane: Avenues to Unusual Boron Cations,

Chem. Sci. 2022, 13, 2303–2309. DOI: 10.1039/D2SC00002D

(Peer-review report)

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